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Nrf2 Induces Interleukin-6 (IL-6) Expression via an Antioxidant Response Element within the IL-6 Promoter

Indeed, formation of an S -sulfonate from water and molecular oxygen, validated by product analysis ( vide infra ), is accompanied by the release of two electrons, as illustrated by the reaction: Since the formation of Fe(0) from a two-electron reduction of Fe(II) is thermodynamically unfeasible, we hypothesize that the released electrons must be accommodated by the sulfonate group itself, forming a two-electron reduced noncanonical sulfonate, which is sufficient to enable thiosulfate formation after the nucleophilic attack by the C408 persulfide (Fig