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H 2 S could be detected by the human nose at a level of 0.1 ppm, a dose of 400-fold lower than its toxic concentrations (Wang, 2002), while long-term exposure can render desensitization of the olfactory nerve to H 2 S (Li et al., 2009)

Polyphenols have the potential to suppress the development of cancer cells through various mechanisms, including interfering with the signaling of growth factor receptors and the cell cycle progression, modulating phosphodiesterase, promoting cellular differentiation and cyclooxygenase pathways, and inhibiting cell signaling kinases

Fasih UH, Cai L, Jeffrey AC, Sardar AC, Jun W, Zhang RZ, Ma WJ, Muhammad F (2021) Cadmium toxicity in plants: impacts and remediation strategies

I dont think the rebounding of serotonin or secondary neurotransmitter systems acting on the levers of personality and cognition, I dont think thats where the answers lie