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FRDA iPSC-derived cardiomyocytes were used to assess the efficacy of the antioxidant idebenone and the iron chelator deferiprone

Theoretical calculations and experiments have shown that by exploiting the dual effects of the N-axial coordination Ru-N 5 and the dual active sites of Ru atoms/clusters, combined with the strong electronic interactions established by the nitrogen-rich coordination of Ru with g-CN, not only modulates the d-band centre of Ru and initiates the electronic localisation and improves the synergistic effect between the active sites, but also enhances the overlapping of the metal d-orbitals with the p-orbitals of oxygen-containing intermediates, which improves the stabilisation of Ru atoms and the adsorption and rapid activation of oxygen-containing intermediates, reducing the reaction activation energy and thus increasing the reaction efficiency

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