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Scheme 2: Synthesis of compound 23 27 General procedure To a solution of N-(5-(((5-(tert-butyl)oxazol-2-yl)methyl)thio)thiazol-2-yl)piperidine-4-carboxamide S1 (26.6 mg, 0.07 mmol, 1.0 eq) in NMP (2 mL) were added bromide S3 (0.070 mmol, 1.0 eq) and DIPEA (0.210 mmol, 3.0 eq), and the reaction was stirred at 50 C overnight