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Yes, for long-term storage, lyophilized (unmixed) GHK-Cu should be kept in a refrigerator or freezer

This study found that the percentage of subjects in three age groups (26 to 49y, 50 to 64y, and 65y and older) with deficient blood levels of vitamin B12 was similar across all age groups but that symptoms of B12 deficiency were not as apparent in younger adults

doi: 10.1148/radiology.177.1.2399339 214 BaeYJKimJ-MSohnC-HChoiJ-HChoiBSSongYSet al

However, the expansion of pathogenic bacteria can break down this barrier, leading to leaky gut and increasing the risk of pathogens entering the lamina propria and bloodstream [33,34,35]